From independent career (Undergraduate co-authors marked with an *):
34) Woodside, A. J.;* Smith, M. A;* Herb, T. M.;* Manor, B. C.; Carroll, P. J. Rablen, P. R.; Graves, C. R. “Synthesis and Characterization of a Tripodal Tris(nitroxide) Aluminum Complex and Its Catalytic Activity toward Carbonyl Hydroboration” Organometallics 2019, 38, 1017–1020. doi.org/10.1021/acs.organomet.8b00933
33) Kirsh, J. M.;* Woodside, A. J.;* Manor, B. C.; Carroll, P. J.; Rablen, P. R.; Graves, C. R. “Synthesis and Characterization of (pyNO−)2GaCl: A Redox-Active Gallium Complex” Inorganics 2018, 6, 50. doi.org/10.3390/inorganics6020050
32) Wilson, H. H.;* Koellner, C. A.;* Hannan, Z. M.;* Endy, C. B.;* Bezpalko, M. W.; Piro, N. A.; Kassel, W. S.; Sonntag, M. D.; Graves, C. R. “Synthesis and Characterization of Neutral Ligand α-Diimine Complexes of Aluminum with Tunable Redox Energetics” Inorg. Chem. 2018, 57, 9622–9633. doi.org/10.1021/acs.inorgchem.8b00045
31) Herb, T. M.;* Poitras, A. M.;* Richardson, K. G.;* Cole, B. E.; Bogart, J. A.; B. E.; Carroll, P. J.; Schelter, E. J.; Graves, C. R. “Synthesis and Characterization of Aluminum Nitroxide Complexes” Polyhedron 2016, 114, 194–199. doi.org/10.1016/j.poly.2015.12.005
30) Poitras, A. M.;* Bogart, J. A.; Cole, B. E.; Carroll, P. J.; Schelter, E. J.; Graves, C. R. “Synthesis and Characterization of Redox-Active Aluminum-Pyridyl Nitroxide Complexes” Inorg. Chem. 2015, 54, 10901–10908. doi.org/10.1021/acs.inorgchem.5b01941
29) Koellner, C. A.;* Piro, N. A.; Kassel, W. S.; Goldsmith, C. R.; Graves, C. R “Synthesis and Characterization of α-Diimine Complexes of Group 13 Metals and Their Catalytic Activity Toward the Epoxidation of Alkenes” Inorg. Chem. 2015, 54, 7239-7141. doi.org/10.1021/acs.inorgchem.5b01136
28) Yeagle, K. P.;* Hester, D.;* Piro, N. A.; Dougherty, W. G.; Kassel, W. S.; Graves, C. R. “Synthesis, Characterization, and Catalytic Activity of a Series of Aluminum-Amidate Complexes” Aust. J. Chem. 2015, 68, 357-365. doi.org/10.1071/CH14514
27) Cole, B. E.;* Wolbach, J. P.; Dougherty, W. G.; Piro, N. A.; Kassel, W. S.; Graves, C. R. “Synthesis and Characterization of Aluminum-α-Diimine Complexes Over Multiple Redox States” Inorg. Chem. 2014, 53, 3899-3906. doi.org/10.1021/ic5003989
From prior work:
26) Thomson, R. K.; Graves, C. R.; Scott, B. L.; Kiplinger, J. L. “Straightforward and efficient oxidation of tris(aryloxide) and tris(amide) uranium(III) complexes using copper(I) halide reagents” Inorg. Chem. Commun. 2011, 14, 1742-1744.
25) Thomson, R. K.; Graves, C. R.; Scott, B. L.; Kiplinger, J. L. “Synthesis and Molecular Structure of (C5Me5)2U(O-tBu)(SePh): A Mixed-Ligand Selenide-Alkoxide Uranium(IV) Metallocene Complex Resulting from tert-Butoxy-Trimethylsilane Elimination” J. Chem. Cryst. 2011, 41, 1241-1244.
24) Thomson, R. K.; Graves, C. R.; Scott, B. L.; Kiplinger, J. L. “Uncovering Alternate Reaction Pathways to Access Uranium(IV) Mixed-Ligand Aryloxide-Chloride and Alkoxide-Chloride Metallocene Complexes: Synthesis and Molecular Structures of (C5Me5)2U(O-2,6-iPr2C6H3)(Cl) and (C5Me5)2U(O-tBu)(Cl)” Inorg. Chim. Acta. 2011, 369, 270-273.
23) Thomson, R. K.; Graves, C. R.; Scott, B. L.; Kiplinger, J. L. “Organometallic Uranium(IV) Fluoride Complexes: Preparation using Protonolysis Chemistry and Reactivity with Trimethylsilyl Reagents” Dalton Trans. 2010, 39, 6826-6831.
22) Schelter, E. J.; Wu, R.; Veauthier, J. M.; Bauer, E. D.; Booth, C. H.; Thomson, R. K.; Graves, C. R.; John, K. D.; Scott, B. L.; Thompson, J. D.; Morris, D. E.; Kiplinger, J. L. “Comparative Study of f-Element Electronic Structure across a Series of Multimetallic Actinide, Lanthanide-Actinide, and Lanthanum-Actinide Complexes Possessing Redox-Active Bridging Ligands” Inorg. Chem. 2010, 49, 1995-2007.
21) Graves, C. R.; Kiplinger, J. L. “Pentavalent Uranium Organometallic Chemistry – Synthetic Pursuit of a Rare Oxidation State” Chem. Commun. 2009, 3831-3853.
20) Thomson, R. K.; Graves, C. R.; Scott, B. L.; Kiplinger, J. L. “Noble Reactions for the Actinides: Safe Gold-Based Access to Organouranium and Azide Complexes” Eur. J. Inorg. Chem. 2009, 1451-1455.
19) Cantat, T.; Graves, C. R.; Scott, B. L.; Kiplinger, J. L. “Challenging the Metallocene Dominance in Actinide Chemistry with a Soft PNP Pincer Ligand: New Uranium Structures and Reactivity Patterns” Angew. Chem., Int. Ed. 2009, 48, 3681-3684.
18) Graves, C. R.; Scott, B. L.; Morris, D. E.; Kiplinger, J. L. “Selenate and Tellurate Complexes of Pentavalent Uranium” Chem. Commun. 2009, 776-778.
17) Graves, C. R.; Vaughn, A. E.; Schelter, E. J.; Scott, B. L.; Thompson, J. D.; Morris, D. E.; Kiplinger, J. L. “Probing the Electronic Structure and Redox Energetics in Pentavalent Organoactinide Complexes” Inorg. Chem. 2008, 47, 11879-11891.
16) Cantat, T.; Graves, C. R.; Jantunen, K. C.; Burns, C. J.; Scott, B. L.; Hay, P. J.; Morris, D. E.; Kiplinger, J. L. “Evidence for the Involvement of 5f-Orbitals in the Bonding and Reactivity of Organometallic Actinide Compounds: Thorium(IV) and Uranium(IV) Bis(hydrazonato) Complexes” J. Am. Chem. Soc. 2008, 103, 17537-17551.
15) Graves, C. R.; Schelter, E. J.; Cantat, T.; Scott, B. L.; Kiplinger, J. L. “A Mild Protocol to Generate Uranium(IV) Mixed-Ligand Metallocene Complexes Using Copper(I) Iodide” Organometallics 2008, 27, 5371-5378.
14) Graves, C. R.; Scott, B. L.; Morris, D. E.; Kiplinger, J. L. “Tetravalent and Pentavalent Uranium Acetylide Complexes Prepared by Oxidative Functionalization with Cu-C≡C-Ph” Organometallics 2008, 27, 3335-3337.
13) Schelter, E. J.; Veauthier, J. M.; Graves, C. R.; John, K. D.; Scott, B. L.; Thompson, J. D.; Morris, D. E.; Kiplinger, J. L. “1,4-Dicyanobenzene as a Scaffold for the Preparation of Multimetallic Actinide Complexes” Chem. Eur. J. 2008, 14, 7782-7790.
12) Pickett, Z. N.; Howard, W. A.; Graves, C. R.; “4-Chloro-2,6-bis(hydroxymethyl)pyridinium Chloride and 4-Dimethylamino-2,6-bis(hydroxymethyl)pyridinium chloride Hemihydrate” J. Chem. Crystallogr. 2008, 38, 717-721.
11) Graves, C. R.; Yang, P.; Kozimor, S. A.; Vaughn, A. E.; Clark, D. L.; Conradson, S. D.; Schelter, E. J.; Scott, B. L.; Thompson, J. D.; Hay, P. J.; Morris, D. E.; Kiplinger, J. L. “Organometallic Uranium(V)-Imido Halide Complexes: From Synthesis to Electronic Structure and Bonding” J. Am. Chem. Soc. 2008, 130, 5272-5285.
10) Graves, C. R.; Morris, D. E.; Scott, B. L.; Kiplinger, J. L. “Facile Access to Pentavalent Uranium Organometallics: One Electron Oxidation of Uranium (IV) Imido Complexes with Copper(I) Salts” J. Am. Chem. Soc. 2007, 129, 11914-11915.
9) Graves, C. R.; Zhou, H.; Stern, C. L.; Nguyen, S. T. “A Mechanistic Investigation of the Asymmetric Meerwein-Schmidt-Ponndorf-Verley (MSPV) Reduction Catalyzed by BINOL/AlMe3 – Structure, Kinetics, and Enantioselectivity” J. Org. Chem. 2007, 72, 9121-9133.
8) Graves, C. R.; Zeng, B. –S; Nguyen, S. T. “Efficient and Selective Oxidation of Alcohols via Al-Based Oppenauer Catalysis” J. Am. Chem. Soc. 2006, 128, 12596-12597.
7) Graves, C. R.; Scheidt, K. A.; Nguyen, S. T. “Enantioselective MSPV Reduction of Ketimines using 2-Propanol and (BINOL)AllII” Org. Lett. 2006, 8, 1229-1232.
6) Graves, C. R.; Campbell, E. J.; Nguyen, S. T. “Aluminum-Based Catalysts for the Asymmetric Meerwein-Schmidt-Ponndorf-Verley-Oppenauer (MSPVO) Reaction Manifold” Tetrahedron: Asymmetry 2005, 16, 3460-3468.
5) Cohen, R.; Graves, C. R.; Nguyen, S, T.; Martin, J. M. L; Ratner, M. A. “The Mechanism of Aluminum-Catalyzed Meerwein-Schmidt-Ponndorf-Verley (MSPV) Reduction of Carbonyls to Alcohols” J. Am. Chem. Soc. 2004, 126, 14796-14803.
4) Graves, C. R.; Merlau, M. L.; Morris, G. A.; Sun, S. -S.; Nguyen, S. T.; Hupp, J. T. “Characterization and Purification of Supramolecular Metal Complexes Using Gel-Permeation Chromatography” Inorg. Chem. 2004, 43, 2013-2017.
3) Read, J. F.; Graves, C. R.; Jackson, E. “The Kinetics and Mechanism of the Oxidation of the Thiols 3-Mercapto-1-propane Sulfonic Acid and 2-Mercaptonicotinic Acid by Potassium Ferrate” Inorg. Chim. Acta 2003, 348, 41-49.
2) King, A. S.; Nikolcheva, L. G.; Graves, C. R.; Kaminski, A.; Vogels, C. M.; Hudson, R. H. E.; Ireland, R. J.; Duffy, S. J.; Westcott, S. A. “Synthesis and Reactivity of Palladium and Platinum Diimine Complexes Containing Boronate Esters” Can J. Chem. 2002, 80, 1217-1222.
1) Read, J. R.; Bewick, S. A.; Graves, C. R.; MacPherson, J. M.; Salah, J. C.; Theriault, A.; Wyand, A. E. H. “The Kinetics and Mechanism of the Oxidation of S-Methyl-L-cysteine, L-Cystine and L-Cysteine by Potassium Ferrate” Inorg. Chim. Acta. 2000, 303, 244-255.
25) Thomson, R. K.; Graves, C. R.; Scott, B. L.; Kiplinger, J. L. “Synthesis and Molecular Structure of (C5Me5)2U(O-tBu)(SePh): A Mixed-Ligand Selenide-Alkoxide Uranium(IV) Metallocene Complex Resulting from tert-Butoxy-Trimethylsilane Elimination” J. Chem. Cryst. 2011, 41, 1241-1244.
24) Thomson, R. K.; Graves, C. R.; Scott, B. L.; Kiplinger, J. L. “Uncovering Alternate Reaction Pathways to Access Uranium(IV) Mixed-Ligand Aryloxide-Chloride and Alkoxide-Chloride Metallocene Complexes: Synthesis and Molecular Structures of (C5Me5)2U(O-2,6-iPr2C6H3)(Cl) and (C5Me5)2U(O-tBu)(Cl)” Inorg. Chim. Acta. 2011, 369, 270-273.
23) Thomson, R. K.; Graves, C. R.; Scott, B. L.; Kiplinger, J. L. “Organometallic Uranium(IV) Fluoride Complexes: Preparation using Protonolysis Chemistry and Reactivity with Trimethylsilyl Reagents” Dalton Trans. 2010, 39, 6826-6831.
22) Schelter, E. J.; Wu, R.; Veauthier, J. M.; Bauer, E. D.; Booth, C. H.; Thomson, R. K.; Graves, C. R.; John, K. D.; Scott, B. L.; Thompson, J. D.; Morris, D. E.; Kiplinger, J. L. “Comparative Study of f-Element Electronic Structure across a Series of Multimetallic Actinide, Lanthanide-Actinide, and Lanthanum-Actinide Complexes Possessing Redox-Active Bridging Ligands” Inorg. Chem. 2010, 49, 1995-2007.
21) Graves, C. R.; Kiplinger, J. L. “Pentavalent Uranium Organometallic Chemistry – Synthetic Pursuit of a Rare Oxidation State” Chem. Commun. 2009, 3831-3853.
20) Thomson, R. K.; Graves, C. R.; Scott, B. L.; Kiplinger, J. L. “Noble Reactions for the Actinides: Safe Gold-Based Access to Organouranium and Azide Complexes” Eur. J. Inorg. Chem. 2009, 1451-1455.
19) Cantat, T.; Graves, C. R.; Scott, B. L.; Kiplinger, J. L. “Challenging the Metallocene Dominance in Actinide Chemistry with a Soft PNP Pincer Ligand: New Uranium Structures and Reactivity Patterns” Angew. Chem., Int. Ed. 2009, 48, 3681-3684.
18) Graves, C. R.; Scott, B. L.; Morris, D. E.; Kiplinger, J. L. “Selenate and Tellurate Complexes of Pentavalent Uranium” Chem. Commun. 2009, 776-778.
17) Graves, C. R.; Vaughn, A. E.; Schelter, E. J.; Scott, B. L.; Thompson, J. D.; Morris, D. E.; Kiplinger, J. L. “Probing the Electronic Structure and Redox Energetics in Pentavalent Organoactinide Complexes” Inorg. Chem. 2008, 47, 11879-11891.
16) Cantat, T.; Graves, C. R.; Jantunen, K. C.; Burns, C. J.; Scott, B. L.; Hay, P. J.; Morris, D. E.; Kiplinger, J. L. “Evidence for the Involvement of 5f-Orbitals in the Bonding and Reactivity of Organometallic Actinide Compounds: Thorium(IV) and Uranium(IV) Bis(hydrazonato) Complexes” J. Am. Chem. Soc. 2008, 103, 17537-17551.
15) Graves, C. R.; Schelter, E. J.; Cantat, T.; Scott, B. L.; Kiplinger, J. L. “A Mild Protocol to Generate Uranium(IV) Mixed-Ligand Metallocene Complexes Using Copper(I) Iodide” Organometallics 2008, 27, 5371-5378.
14) Graves, C. R.; Scott, B. L.; Morris, D. E.; Kiplinger, J. L. “Tetravalent and Pentavalent Uranium Acetylide Complexes Prepared by Oxidative Functionalization with Cu-C≡C-Ph” Organometallics 2008, 27, 3335-3337.
13) Schelter, E. J.; Veauthier, J. M.; Graves, C. R.; John, K. D.; Scott, B. L.; Thompson, J. D.; Morris, D. E.; Kiplinger, J. L. “1,4-Dicyanobenzene as a Scaffold for the Preparation of Multimetallic Actinide Complexes” Chem. Eur. J. 2008, 14, 7782-7790.
12) Pickett, Z. N.; Howard, W. A.; Graves, C. R.; “4-Chloro-2,6-bis(hydroxymethyl)pyridinium Chloride and 4-Dimethylamino-2,6-bis(hydroxymethyl)pyridinium chloride Hemihydrate” J. Chem. Crystallogr. 2008, 38, 717-721.
11) Graves, C. R.; Yang, P.; Kozimor, S. A.; Vaughn, A. E.; Clark, D. L.; Conradson, S. D.; Schelter, E. J.; Scott, B. L.; Thompson, J. D.; Hay, P. J.; Morris, D. E.; Kiplinger, J. L. “Organometallic Uranium(V)-Imido Halide Complexes: From Synthesis to Electronic Structure and Bonding” J. Am. Chem. Soc. 2008, 130, 5272-5285.
10) Graves, C. R.; Morris, D. E.; Scott, B. L.; Kiplinger, J. L. “Facile Access to Pentavalent Uranium Organometallics: One Electron Oxidation of Uranium (IV) Imido Complexes with Copper(I) Salts” J. Am. Chem. Soc. 2007, 129, 11914-11915.
9) Graves, C. R.; Zhou, H.; Stern, C. L.; Nguyen, S. T. “A Mechanistic Investigation of the Asymmetric Meerwein-Schmidt-Ponndorf-Verley (MSPV) Reduction Catalyzed by BINOL/AlMe3 – Structure, Kinetics, and Enantioselectivity” J. Org. Chem. 2007, 72, 9121-9133.
8) Graves, C. R.; Zeng, B. –S; Nguyen, S. T. “Efficient and Selective Oxidation of Alcohols via Al-Based Oppenauer Catalysis” J. Am. Chem. Soc. 2006, 128, 12596-12597.
7) Graves, C. R.; Scheidt, K. A.; Nguyen, S. T. “Enantioselective MSPV Reduction of Ketimines using 2-Propanol and (BINOL)AllII” Org. Lett. 2006, 8, 1229-1232.
6) Graves, C. R.; Campbell, E. J.; Nguyen, S. T. “Aluminum-Based Catalysts for the Asymmetric Meerwein-Schmidt-Ponndorf-Verley-Oppenauer (MSPVO) Reaction Manifold” Tetrahedron: Asymmetry 2005, 16, 3460-3468.
5) Cohen, R.; Graves, C. R.; Nguyen, S, T.; Martin, J. M. L; Ratner, M. A. “The Mechanism of Aluminum-Catalyzed Meerwein-Schmidt-Ponndorf-Verley (MSPV) Reduction of Carbonyls to Alcohols” J. Am. Chem. Soc. 2004, 126, 14796-14803.
4) Graves, C. R.; Merlau, M. L.; Morris, G. A.; Sun, S. -S.; Nguyen, S. T.; Hupp, J. T. “Characterization and Purification of Supramolecular Metal Complexes Using Gel-Permeation Chromatography” Inorg. Chem. 2004, 43, 2013-2017.
3) Read, J. F.; Graves, C. R.; Jackson, E. “The Kinetics and Mechanism of the Oxidation of the Thiols 3-Mercapto-1-propane Sulfonic Acid and 2-Mercaptonicotinic Acid by Potassium Ferrate” Inorg. Chim. Acta 2003, 348, 41-49.
2) King, A. S.; Nikolcheva, L. G.; Graves, C. R.; Kaminski, A.; Vogels, C. M.; Hudson, R. H. E.; Ireland, R. J.; Duffy, S. J.; Westcott, S. A. “Synthesis and Reactivity of Palladium and Platinum Diimine Complexes Containing Boronate Esters” Can J. Chem. 2002, 80, 1217-1222.
1) Read, J. R.; Bewick, S. A.; Graves, C. R.; MacPherson, J. M.; Salah, J. C.; Theriault, A.; Wyand, A. E. H. “The Kinetics and Mechanism of the Oxidation of S-Methyl-L-cysteine, L-Cystine and L-Cysteine by Potassium Ferrate” Inorg. Chim. Acta. 2000, 303, 244-255.